Laboratoire de chimie de la matière condensée de Paris
Tour 44-43 / 4ème étage
Case courrier 174
4, Place Jussieu
75005 PARIS
France

Dr. François RIBOT

Directeur(trice) de Recherche
NANO

francois.ribot(@-Code a retirer pour éviter le SPAM-)sorbonne-universite.fr
bureau 34-44-418

François Ribot was born in 1962. He graduated from Ecole Supérieure de Physique et Chimie Industrielle (ESPCI) in 1986. He then received his PhD in inorganic chemistry in 1990 from Pierre et Marie Curie University (UPMC), now part of Sorbonne University. His work, performed under the supervision of Pr. C. Sanchez and financed by Rhone-Poulenc Company, dealt with the sol-gel process of yttrium(III) and cerium(IV) oxides. During his PhD, he spent 16 months as a research associate in the group of Pr. Egon Matijevic at Clarkson University (Potsdam, NY, USA), working on the synthesis of uniform sub-micronic mixed colloids of yttrium(III) and copper(II) compounds. He joined the CNRS in 1990 and has been working since at the Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP-UMR 7574). In 2010, F. Ribot obtained his habilitation to lead research from Pierre et Marie Curie University (UPMC). He co-authored more than 100 peer reviewed papers.

His research deals with the chemistry of materials. He has contributed to the fields of sol-gel by studying the role of complexing ligands on the reactivity of various metals alkoxydes. He then worked on hybrid organic-inorganic materials and more particularly on those designed by the nanobulding blocks approach from organotin oxo-clusters. He also collaborated with industrial partners on the nanotexturation of hybrid coatings and the controlled precipitation of cerium(IV) phosphates. Over the last years, he shifted his research focus toward gold nanoparticles with two main topics: the synthesis of N-heterocyclic carbene stabilized gold nanoparticles and the in-situ study of their functionalization.

NMR spectroscopy constitutes an important tool in his researches and he developed strategies based on diffusion ordered spectroscopy (DOSY) experiments to study the interface of various nano-objects, ranging from molecularly defined oxo-clusters to nanoparticles, in solution or in suspension.

Last update 2020/01/07

Alexandre Porcheron, « Coordination complexes grafted on plasmonic nanoparticles », Sorbonne Université, started October 2018 – financed by ANR COCOsMEN, PhD adviser, co-supervised with L. Fensterbank.
Victoire Asila, « N-heterocyclic carbene-stabilized gold nanoclusters », Sorbonne Université, started October 2018 – financed by ED397, co-supervised with C. Chanéac (PhD adviser).
Laura Hippolyte, « New syntheses of N-heterocyclic carbene-stabilized gold nanoparticles », UPMC, 26/11/2018 – financed by Labex MiChem, ED 397 and Labex Matisse, PhD adviser, co-supervised with L. Fensterbank.
Perrot Alexandre, « Sol-gel coatings incorporating active mesostructured particles obtained by spray drying for aeronautical aluminum alloys protection against corrosion », UPMC, 2/6/2015 – financed by ANR AERO², PhD adviser, co-supervised with L. Nicole.
Ben Sassi Hanen, « Probing, in suspension, the ligands on the surface of gold nanoparticles by DOSY NMR », UPMC, 28/2/2013 – financed by MESR, PhD adviser.
Letailleur Alban, « Pattering of hybrid silica coatings by nanoimprint : applications to light extractions », UPMC, 15/3/2012 – financed by Saint-Gobain Recherche, co-supervised with C. Boissière and C. Sanchez (PhD adviser).
Monget Julie, « Hybrid sol-gel coating for the corrosion protection of aeronautical aluminium alloys », UPMC, 14/12/2010 – financed by EADS-IW, co-supervised with L. Nicole and C. Sanchez (PhD adviser).
Nazaraly Micaela, « Control of structure, morphology and size of cerium(IV) phosphate particles », UPMC, 24/10/2006 – financed by Rhodia, co-supervised with C. Chanéac and J.-P. Jolivet (PhD adviser).
De Monredon Sophie, « Organosilanes/precipited silica interaction from hydroalcoolic to aqueous medium », UPMC, 7/12/2004 – financed by Rhodia, co-supervised with C. Bonhomme and F. Babonneau (PhD adviser).
Eychenne-Baron Christophe, « New syntheses of the macrocation {(BuSn)₁₂O₁₄(OH)₆}²⁺: use as nanobrick for the synthesis. of hybrid materials », UPMC, 11/5/2001 – financed by MRT, co-supervised with C. Sanchez (PhD adviser).
Banse Frédéric, « Hydrolysis-condensation of monorganotin trialkoxides: synthesis of hybrid organic-inorganic systems », UPMC, 20/10/1995 – financed by MRT, co-supervised with C. Sanchez (PhD adviser).

Last update 2020/01/05

Nathalie Bridonneau, « Synthesis of N-heterocyclic carbene-stabilized gold nanoparticles », 1/9/2016-31/8/2017, ATER UPMC.
Anne Soleilhavoup, « Probing, by multinuclear NMR, the integrity and mobility of organotin oxo-clusters inserted in lipidic membranes », 5/1/2015-29/2/2016, ANR MEMINT.
Baradari Hiva, « Mineral and hybrid additives for Portland cement », 15/2/2012-31/8/2013, financed by Chryso.
Becuwe Matthieu, « Portland cement based hybrid materials », 1/9/2010-31/8/2011, financed by Chryso.
Van Lokeren Luk, « Pulsed field gradient based NMR methodology to probe, in suspension, the affinity of an organic ligand for nanoparticles surface », 1/9/2009-29/2/2012, ANR EVALON (ANR-08-NANO-026).
Van der Beek David, « New hybrid organic-inorganic liquid crystals based on nano building units », 2/11/2005-15/7/2007, EU(FP6-Marie Curie Mobility Actions) HYBRIDLICRYST.
Martinez-Ferrero Eugenia, « New tin(IV) based-nanobricks for hybrid materials », 1/10/2003-31/1/2005, EU(FP5-HP) NBB-Hybrids.
Armelao Lidia, « Sol-process prepared tin oxide », 1/4/1995-31/3/1996, grant from the University of Padova (Italy).
Kehr Gerald, « Monoorganotin based hybrid systems », 3/4/1995-2/2/1996, EU(FP3-HCM) CHRX940610.

Last update 2020/01/05

L. Angiolini, D. Caretti (Universita degli Studi di Bologna, Bologne, Italy): Organotin based hybrid materials
D. Constantin, B. Pansu, (LPS – UMR 8502, Orsay): Inclusions in lipid membranes, gold nanoparticles
D. Dakternieks (Deakin University, Geelong, Australia): Organotin oxo-clusters chemistry
S. Diré (Universita di Trento, Trente, Italy): Silsesquioxane based NBB and hybrid materials
B. Dubertret, N. Lequeux, T. Pons (LPEM – UMR 8213, ESPCI, Paris): Probing the functionalization of QD by NMR
L. Fensterbank, B. Fleury, D. Lesage (IPCM – UMR 8232, Sorbonne-Université, Paris): NHC stabilized gold nanoparticles and clusters
B. Jousseaume, T. Toupance (ISM – UMR 5255, Université de Bordeaux, Talence): Organotin based hybrid materials
M. Kahn, B. Chaudret (LCC – UPR 8241, Toulouse): Probing the functionalization of nanoparticles by DOSY NMR
T. Lalot (HiCSA – EA 4100, Panthéon Sorbonne, Paris): Hybrid materials
M. Lejeune (IRCER – UMR 7315, Université de Limoges, Limoges): ²⁹Si NMR characterization of sol-gel inks
J.C. Martins (Ghent Universiteit, Ghent, Belgium): Advanced ¹¹⁹Sn NMR and DOSY NMR
L. Matejka, A. Strachota (IMC, Prague, Czech Republic): Organotin oxo-clusters based hybrid materials
D. Mercier (IRCP – UMR 8247, ENSCP, Paris): NHC modified surfaces
N. Mézailles (LHFA – UMR 5069, Université Paul Sabatier, Toulouse): DOSY NMR
G. Morris (Manchester University, Manchester, UK): DOSY NMR
A.-L. Rollet (PHENIX – UMR 8234, Sorbonne Université, Paris) : DOSY NMR with uncommon nuclei
C. Schatz (LPCO – UMR 5629, ENSCBP, Bordeaux): DOSY NMR on polyelectrolytes solutions and coacervates
N. Steunou (ILV – UMR 8180, Université Versailles Saint Quentin en Yvelines, Versailles): Vanadium oxide nanotubes
O. Tillement (ILM – UMR 5306, Université Claude Bernard, Villeurbanne): ultra-small multifunctional Gd-based silica nanoparticles
R. Willem (Vrije Universiteit Brussel, Brussels, Belgium): Advanced multinuclear NMR

Last update 2020/01/07

last update 2020/07/09

The macrocation {(RSn)₁₂O₁₄(OH)₆}²⁺

*Its oxo-metallic framework, as determined by single crystal X-ray diffraction on several compounds, correspond to a quasi spherical cage made of an equal number of six-coordinated tin atoms (Sn*_H) and five-coordinated tin atoms (Sn_P) linked by µ₃*-O and µ*₂*-OH bridges. This framework, which is perfectly stable in solution, gives a* **distinct ¹¹⁹Sn-{¹H} NMR signature**, composed of two signals (one for each coordination) and four coupling constants in line with the different connection paths. One positive charge is located at each pole formed by the six-coordinated tin atoms and the µ₂*-OH bridges (Inorg. Chem.* **1995***, 34, 6371-6379 ; Organometallics* **2000***, 19, 1940-1949 ; J. Mater. Chem.* **2005***, 15, 3973-3978).*

Various organizations of {(BuSn)₁₂O₁₄(OH)₆}²⁺ encountered in the solid state.

In **{(BuSn)₁₂O₁₄(OH)₆}(O₂PPh₂)₂(H₂O)₂**, chains are formed by bridging diphenylphosphinate anions (unpublished result).
In **{(BuSn)₁₂O₁₄(OH)₆}(pTS)₂(C₄H₈O₂)₂**, the chains, formed by bridging p-toluenesulfonate anions, are assembled in plane by dioxane molecules, which interact with five-coordinated tin atoms (*Organometallics* **2000**, 19, 1940-1949).
In **{(BuSn)₁₂O₁₄(OH)₆}(CHAPS)₂**, the chains, formed by a complex set of electrostatic contacts between the 3-cyclohexylamino-1-propanesulfonate anions and the µ₂-OH groups of the macrocation, are assembled in planes through hydrogen bonds involving the amino and the sulfonate groups (unpublished result).
In **{(BuSn)₁₂O₁₄(OH)₆}(AMPS)₂**, -NH•••O=C(R)-NH•••O=C(R)- hydrogen bonds yield right and left helices, which are assembled in a 3D framework by a complex set of electrostatic contacts between the 2-acrylamido-2-methyl-1-propanesulfonate anions and the µ₂-OH of the macrocation (*J. Mater. Chem.* **2005**, 15, 3973-3978).

Sn₁₂(μ₃-O)₆(μ₂-O)₂(μ₂-OH)₄(μ₂-OEt)₁₀(OEt)₁₈(HOEt)₄

Its centrosymmetric oxo-metallic framework and the location of the ethoxy groups have been first determined by single crystal X-ray diffraction. Then, with advanced multinuclear solution state NMR experiments, such as ¹H-¹¹⁹Sn HSQC, four bridging hydroxy groups (µ₂-OH) have been localized. Finally, a closer look at the O•••O distances has identified four pseudo bidentate « EtOH•••OEt » bridging groups. This tin oxo-cluster is perfectly stable in solution (*Inorg. Chem.* **2008**, 47, 5831-5840).

Last update 2020/01/05

Strategies to functionalise and assemble the macrocation {(RSn)₁₂O₁₄(OH)₆}²⁺

In the nano building block (NBB) approach to hybrid materials from the oxo-cluster {(RSn)₁₂O₁₄(OH)₆}²⁺, several functionalization and assembling strategies have been explored. They mainly vary by the method use to introduce the functional groups amenable to link the clusters (eg. by polymerization) or to react with a complementary NBB. A first one uses the strong and covalent Sn-C(sp3) bond. A second one takes advantage of the positive charge localized at each pole of this NBB (*New J. Chem.* **1995**, 19, 1145-1153; *J. Sol-Gel Sci. Tech.* **1997**, 8, 529-533; *Comm. Inorg. Chem.* **1999**, 20, 327-371; *Chem. Mater.* **2001**, 13, 3061-3083; *Adv. Mater.* **2002**, 14, 1496-1499; *J. Mater. Chem.* **2005**, 15, 3973-3978; *Polym. Chem.* **2014**, 5, 4474-4479; *Macromolecules* **2014**, 47, 4266-4287).

Last update 2020/01/05

Coordination complexes grafted on metallic nanoparticles: toward synergy

ANR COCOsMEN

N-heterocyclic carbene-stabilized gold nanoparticles

N-heterocyclic carbenes (NHC), which form strong and covalent bonds with various metals, constitute a rich class of caping ligands, more and more studied in the field of nanoparticles. We proposed a simple and straightforward synthesis of NHC-stabilized gold nanoparticles from (benz)imidazolium-AuX₄ *complexes and NaBH*₄ *only. The method allows size tuning, from 3 to 6 nm, by adding (benz)imidazolium bromide. Changing the reducing agent to tBuNH*₂BH₃ *shifts the size range to ca. 6-12 nm. A one pot protocol was also reported from AuCl, (benz)imidazolium bromides and NaBH*₄, thereby delivering an even more straightforward way of producing NHC-capped gold nanoparticles. In addition, X-ray photoelectron spectroscopy (XPS) unambiguously evidenced, on the nanoparticles, the covalent bond formed between the NHC and the surface gold atoms (Dalton Trans. **2018***, 47, 6850-6859).*

Quantified binding scale of competing ligands on the surface of thiols stabilized gold nanoparticles

Partially exchanging the surface ligands is a convenient way to modulate the properties of nanoparticles. However, the surface composition at equilibrium usually does not match the solution composition. For thiols stabilized gold nanoparticles, the concentrations of the initial and new ligands, in their free and grafted forms, can be monitored by ¹H NMR. The constant K, which rules the partition of both ligands between the solution and the surface, can be determined from the equilibrium concentrations. K depends on the pair of ligands and on the particles size (*ACS Nano* **2015**, 9, 7572-7582; *Small* **2017**, 13, 1604028).

Last update 2020/01/05

Pulsed Field Gradient NMR basis

**Pulsed field gradient (PFG) NMR spectroscopy or DOSY (Diffusion Ordered SpectroscopY)** is a way of measuring diffusion coefficient for each component in a solution. The method is based on a series of spin echo or stimulated spin echo experiments, in which the gradient strength is increased. According to the equation derived by Stejskal and Tanner in 1965, the signal intensities depend on the diffusion coefficient and on parameters related to the studied nucleus (gyromagnetic ratio) or set by the experimenter (gradient strength, diffusion delay and gradient pulses length). Data can be processed in several ways. For instance, plotting the logarithm of the echo intensity versus the square of the gradient strength for each chemical signal yields, in simple cases, straight lines, the slopes of which are proportional to the diffusion coefficients. Alternatively, a global processing of the data can yield 2D DOSY maps where one axis corresponds to the usual NMR spectroscopic dimension and the other one to a dimension along which species are spread according to their diffusion behavior. In the example presented, two types of TOPO (trioctylphosphine oxide) molecules can be differentiated by their diffusion: those anchored on the surface of CdSe quantum dots and those free in solution.

Probing the ionic association on {(BuSn)₁₂O₁₄(OH)₆}X₂

*The possibility to individually monitor the diffusion coefficient of multiple anionic and cationic species in mixtures allowed us to evidence ion exchange. Thus when [(BuSn)*₁₂O₁₄*(OH)*₆*](pTS)*₂ *(pTS=p‐toluenesulfonate) is mixed with two equivalents of [NMe*₄*]Ph*₂PO₂*, pTS*⁻ *is displaced by Ph*₂PO₂⁻*, even though there is no evidence of ionic dissociation. This example clearly illustrates the potential of pulsed field gradient* ¹*H NMR spectroscopy in inorganic/organometallic chemistry, to follow preferential ion pairing in multi‐ion systems at the level of each individually charged species (Chem. Eur. J.* **2004***, 10, 1747-1751).*

Looking at the functionalization of Ti₁₆O₁₆(OEt)₃₂

The titanium oxo-cluster Ti₁₆O₁₆(OEt)₃₂ can be functionalized by exchanging some of its surface ethoxy groups by other hydroxylated molecules. When the entering molecules are hydroxyl-terminated long polymers, the outcome of the exchange reaction is difficult to infer. 1H DOSY NMR shows that part of the added polymers remains free but also that part of them get grafted to the oxo-metallic core, what yields larger species with a smaller diffusion coefficient (*J. Mater. Chem.* **2011**, 21, 4470-4475; *J. Poly. Sci. A* **2011**, 49, 2636-2644).

Ligands interacting with sol-gel prepared nano-TiO₂

Suspensions of titanium dioxide nanoparticles (~3 nm), prepared by hydrolysis-condensation of titanium tetrabutoxide in the presence of acetylacetone (AcacH), p-toluene sulfonic acid (pTSH) and n-butanol (BuOH), have been characterized by diffusion ordered NMR spectroscopy (DOSY NMR). The Acac(H), which is added in the process to act as a blocking ligand, can be found grafted (enol form) to the nanoparticles or free (enol form in equilibrium with the ketone form). The pTS(H), which is added to catalyze the hydrolysis-condensation, also interacts with the nanoparticles once they are formed. Part of the pTS(H) is strongly bound to the surface, likely through the sulfonate head group, while the other part corresponds to free pTS(H) in rapid exchange with molecules weakly interacting with the nanoparticles (*Chem. Eur. J*. **2007**, 13, 6957-6966).

Quantitative analysis of mixtures

Pulsed Field-Gradient Spin Echo (PGSE) NMR, which associates to a spectral dimension the measure of diffusion coefficients, is a convenient technique for mixture analysis. Unfortunately, because of relaxation effects, the quantification by PGSE NMR is far from straightforward for mixtures with strong spectral overlap. By explicitly including the relaxation effects in the Stejskal and Tanner equation, meaningful fractions can be obtained from a multicomponent fit of the PGSE attenuation. This approach is illustrated with a binary mixture of polystyrenes, the ¹H NMR spectra of which are perfectly identical. Fractions with error lower than 3% are obtained. The T₁ and T₂ values, required for this analysis, are either independently measured with conventional sequences or determined, along with the fractions and the diffusion coefficients, from the simultaneous analysis of up to 6 PGSE data sets recorded with different diffusion delays (*J. Magn. Reson.* **2013**, *231*, 46-53).

Dynamics at the cross-linking nodes in hybrid self-healing materials

Self-healing elastomers, based on electrostatic cross-linking, can be prepared from butyl acrylate and the organotin NBB {(BuSn₁₂O₁₄(OH)₆}(AMPS)₂. The dynamics at the cross-linking nodes, which is responsible of self-healing, has been evidenced by DOSY NMR on a swollen hybrid material doped with a non-functional version of the organotin NBB, *{(BuSn*₁₂O₁₄*(OH)*₆*}(pTS)*₂. The difference observed between the diffusion coefficient of the butyltin oxo-core, measured by ¹¹⁹Sn DOSY NMR, and its charge compensating anions (pTS), measured by ¹H DOSY NMR, clearly reveals the exchange taking place at the cross-linking nodes (*Polym. Chem.* **2014**, 5, 4474-4479).

Last update 2020/01/06

Journal articles

ref_biblio: Ryma Haddad, Yingrui Zhao, Antoine Miche, Ferdaous Ben Romdhane, Nivedita Sudheer, et al.. Solvent-free Preparation of Ru/Al 2 O 3 Catalysts for CO 2 Methanation: An Example of Frugal Innovation. Chemistry of Materials, 2023, 35 (19), pp.8248-8260. ⟨10.1021/acs.chemmater.3c01746⟩. ⟨hal-04257377⟩
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ref_biblio: Alexandre Porcheron, Omar Sadek, Salem Ba Sowid, Nathalie Bridonneau, Laura Hippolyte, et al.. Direct Synthesis of Mesoionic Carbene (MIC)-Stabilized Gold Nanoparticles from 1,2,3-Triazolium Salts. Chemistry of Materials, 2023, 35 (17), pp.6865-6876. ⟨10.1021/acs.chemmater.3c01162⟩. ⟨hal-04185135v2⟩
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ref_biblio: Laura Hippolyte, Omar Sadek, Salem Ba Sowid, Alexandre Porcheron, Nathalie Bridonneau, et al.. N-Heterocyclic Carbene Boranes: Dual Reagents for the Synthesis of Gold Nanoparticles. Chemistry - A European Journal, 2023, 29, pp.e202301610. ⟨10.1002/chem.202301610⟩. ⟨hal-04116921⟩
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ref_biblio: Rémi André, Alberto Palazzolo, Cyprien Poucin, François Ribot, Sophie Carenco. Phosphine-Catalyzed Activation of Phenylsilane for Benzaldehyde Reduction. ChemPlusChem, 2023, 88 (5), pp.e202300038. ⟨10.1002/cplu.202300038⟩. ⟨hal-04032358⟩
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ref_biblio: Mercedes Perullini, Sophie Dulhoste, François Ribot, Gérard Pehau-Arnaudet, Odile M.M. Bouvet, et al.. Bacteria metabolic adaptation to oxidative stress: the case of silica. Journal of Biotechnology, 2023, 374, pp.80-89. ⟨10.1016/j.jbiotec.2023.08.002⟩. ⟨hal-04185169⟩
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ref_biblio: Shakir Bin Mujib, François Ribot, Christel Gervais, Gurpreet Singh. Self-supporting carbon-rich SiOC ceramic electrodes for lithium-ion batteries and aqueous supercapacitors. RSC Advances, 2021, 11 (56), pp.35440-35454. ⟨10.1039/d1ra05968h⟩. ⟨hal-03412976⟩
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ref_biblio: Iban Azcarate, Wei Yin, Christophe Méthivier, François Ribot, Christel Laberty-Robert, et al.. Assessing the Oxidation Behavior of EC:DMC Based Electrolyte on Non- Catalytically Active Surface. Journal of The Electrochemical Society, 2020, 167 (8), pp.080530. ⟨10.1149/1945-7111/ab8f57⟩. ⟨hal-02640318⟩
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ref_biblio: Beata Strachota, Adam Strachota, Sabina Horodecka, Miloš Steinhart, Jana Kovářová, et al.. Polyurethane nanocomposites containing the chemically active inorganic Sn-POSS cages. Reactive and Functional Polymers, 2019, 143, pp.104338. ⟨10.1016/j.reactfunctpolym.2019.104338⟩. ⟨hal-02322112⟩
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ref_biblio: Brindusa Dragoi, Guillaume Laurent, Sandra Casale, Taissire Benamor, Bénédicte Lebeau, et al.. Stability and degradation of PEO₂₀PPO₇₀PEO₂₀ triblock copolymers in mesostructured silica. Journal of Sol-Gel Science and Technology, 2019, 91 (3), pp.552-566. ⟨10.1007/s10971-019-05044-w⟩. ⟨hal-02175149⟩
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ref_biblio: P. Gorbovyi, A.P. Diaz-Gomez, M. Traore, L. Museur, L. Rozes, et al.. Alkoxysilane effect in hybrid material: A comparison of pHEMA-TiO2 and pMAPTMS-TiO2 nanoparticulate hybrids. Materials Research Bulletin, 2019, 114, pp.130-137. ⟨10.1016/j.materresbull.2019.02.013⟩. ⟨hal-02405840⟩
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ref_biblio: Xavier Frogneux, Antoine Pesesse, Simon Delacroix, François Ribot, Sophie Carenco. Radical‐Initiated Dismutation of Hydrosiloxanes by Catalytic Potassium‐Graphite. ChemCatChem, 2019, 11, pp.1-6. ⟨10.1002/cctc.201900172⟩. ⟨hal-02155557⟩
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ref_biblio: Manon Debayle, Elie Balloul, Fatimata Dembele, Xiangzhen Xu, Mohamed Hanafi, et al.. Zwitterionic polymer ligands: An ideal surface coating to totally suppress protein-nanoparticle corona formation?. Biomaterials, 2019, 219, pp.119357. ⟨10.1016/j.biomaterials.2019.119357⟩. ⟨hal-02189463⟩
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ref_biblio: Xavier Frogneux, Laura Hippolyte, Dimitri Mercier, David Portehault, Corinne Chanéac, et al.. Direct Synthesis of N-Heterocyclic Carbene-Stabilized Copper Nanoparticles from a N-Heterocyclic Carbene-Borane. Chemistry - A European Journal, 2019, 25 (49), pp.11481-11485. ⟨10.1002/chem.201901534⟩. ⟨hal-02167204⟩
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ref_biblio: N. Bridonneau, L. Hippolyte, D. Mercier, D. Portehault, M. Desage-El Murr, et al.. N-Heterocyclic carbene-stabilized gold nanoparticles with tunable sizes. Dalton Transactions, 2018, 47 (19), pp.6850 - 6859. ⟨10.1039/C8DT00416A⟩. ⟨hal-01867971⟩
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ref_biblio: Sandra Dirè, Davide Bottone, Emanuela Callone, Devid Maniglio, Isabelle Génois, et al.. Hydrophobic Coatings by Thiol-Ene Click Functionalization of Silsesquioxanes with Tunable Architecture. Materials, 2017, 10 (8), pp.913. ⟨10.3390/ma10080913⟩. ⟨hal-01581190⟩
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ref_biblio: Claire Goldmann, François Ribot, Leonardo F. Peiretti, Paola Quaino, Frederik Tielens, et al.. Quantified Binding Scale of Competing Ligands at the Surface of Gold Nanoparticles: The Role of Entropy and Intermolecular Forces. Small, 2017, 13 (20), pp.1604028 ⟨10.1002/smll.201604028⟩. ⟨hal-01517528⟩
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ref_biblio: Santosh Kumar Meena, Claire Goldmann, Douga Nassoko, Mahamadou Seydou, Thomas Marchandier, et al.. Nanophase Segregation of Self-Assembled Monolayers on Gold Nanoparticles. ACS Nano, 2017, 11 (7), pp.7371-7381. ⟨10.1021/acsnano.7b03616⟩. ⟨hal-01543644⟩
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ref_biblio: Julie Besnardiere, Xavier Petrissans, François Ribot, Valérie Briois, Christine Surcin, et al.. Nanoparticles of Low-Valence Vanadium Oxyhydroxides: Reaction Mechanisms and Polymorphism Control by Low-Temperature Aqueous Chemistry. Inorganic Chemistry, 2016, 55 (21), pp.11502 - 11512. ⟨10.1021/acs.inorgchem.6b02059⟩. ⟨hal-01395197⟩
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ref_biblio: Danielle Laurencin, François Ribot, Christel Gervais, Adrian J. Wright, Annabelle Baker, et al.. 87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks. ChemistrySelect, 2016, 1 (15), pp.4509-4519. ⟨10.1002/slct.201600805⟩. ⟨hal-01378175⟩
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ref_biblio: Evgeny Borovin, Emanuela Callone, François Ribot, Sandra Diré. Mechanism and Kinetics of Oligosilsesquioxane Growth in the In Situ Water Production Sol–Gel Route: Dependence on Water Availability. European Journal of Inorganic Chemistry, 2016, Advanced Complex Inorganic Nanomaterials, 2016 (13-14), pp.2166-2174. ⟨10.1002/ejic.201501220⟩. ⟨hal-01291296⟩
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ref_biblio: Krzysztof Rodzen, Adam Strachota, François Ribot, Libor Matejka, Jana Kovarova, et al.. Reactivity of the tin homolog of POSS, butylstannoxane dodecamer, in oxygen-induced crosslinking reactions with an organic polymer matrix: Study of long-time behavior. Polymer Degradation and Stability, 2015, 118, pp.147-166. ⟨10.1016/j.polymdegradstab.2015.04.020⟩. ⟨hal-01291243⟩
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ref_biblio: Claire Goldmann, Rémi Lazzari, Xavier Paquez, Cédric Boissière, François Ribot, et al.. Charge Transfer at Hybrid Interfaces: Plasmonics of Aromatic Thiol-Capped Gold Nanoparticles. ACS Nano, 2015, 9 (7), pp.7572-7582. ⟨10.1021/acsnano.5b02864⟩. ⟨hal-01291241⟩
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ref_biblio: Adam Strachota, Krzysztof Rodzen, Vladimir Raus, François Ribot, Miroslav Janata, et al.. Incorporation and chemical effect of Sn-POSS cages in poly(ethyl methacrylate). European Polymer Journal, 2015, 68 (SI), pp.366-378. ⟨10.1016/j.eurpolymj.2015.04.024⟩. ⟨hal-01291242⟩
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ref_biblio: Krzysztof Rodzen, Adam Strachota, François Ribot, Miroslav Slouf. Effect of network mesh size on the thermo-mechanical properties of epoxy nanocomposites with the heavier homologue of POSS, the inorganic butylstannoxane cages. European Polymer Journal, 2014, 57, pp.169-181. ⟨10.1016/j.eurpolymj.2014.05.016⟩. ⟨hal-01289948⟩
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ref_biblio: Adam Strachota, Krzysztof Rodzen, François Ribot, Magdalena Perchacz, Miroslava Trchova, et al.. Tin-based “super-POSS” building blocks in epoxy nanocomposites with highly improved oxidation resistance. Polymer, 2014, 55 (16, SI), pp.3498-3515. ⟨10.1016/j.polymer.2014.06.002⟩. ⟨hal-01289947⟩
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ref_biblio: Adam Strachota, Krzysztof Rodzen, François Ribot, Miroslava Trchova, Milos Steinhart, et al.. Behavior of Tin-Based ``Super-POSS'' Incorporated in Different Bonding Situations in Hybrid Epoxy Resins. Macromolecules, 2014, 47 (13), pp.4266-4287. ⟨10.1021/ma500507j⟩. ⟨hal-01289945⟩
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ref_biblio: C. Sanchez, C. Boissière, S. Cassaignon, Corinne Chanéac, O. Durupthy, et al.. Molecular Engineering of Functional Inorganic and Hybrid Materials. Chemistry of Materials, 2014, 26 (1, SI), pp.221-238. ⟨10.1021/cm402528b⟩. ⟨hal-01289918⟩
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ref_biblio: Olivier Fontaine, Amina Touidjine, Manuel Maréchal, Christian Bonhomme, François Ribot, et al.. One−pot Route To Class II Hybrid Ionogels Electrolytes. New Journal of Chemistry, 2014, 38 (5), pp.2008-2015. ⟨10.1039/C3NJ01272G⟩. ⟨hal-00922351⟩
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ref_biblio: Basma Khadro, Imane Baroudi, Anne-Marie Goncalves, Bruno Berini, Bruce Pegot, et al.. Interfacing a heteropolytungstate complex and gelatin through a coacervation process: design of bionanocomposite films as novel electrocatalysts.. Journal of Materials Chemistry A, 2014, 2 (9208-9220), pp.9208-9220. ⟨10.1039/c4ta01142b⟩. ⟨hal-01002760⟩
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ref_biblio: F. Potier, A. Guinault, S. Delalande, C. Sanchez, F. Ribot, et al.. Nano-building block based-hybrid organic-inorganic copolymers with self-healing properties. Polymer Chemistry, 2014, 5 (15), pp.4474-4479. ⟨10.1039/c4py00172a⟩. ⟨hal-01289920⟩
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ref_biblio: Luk van Lokeren, Hanen Ben Sassi, Guy van Assche, François Ribot. Quantitative analysis of polymer mixtures in solution by pulsed field-gradient spin echo NMR spectroscopy. Journal of Magnetic Resonance, 2013, 231, pp.46-53. ⟨10.1016/j.jmr.2013.03.003⟩. ⟨hal-01289774⟩
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ref_biblio: Anna Mignot, Charles Truillet, François Lux, Lucie Sancey, Cédric Louis, et al.. A top-down synthesis route to ultrasmall multifunctional Gd-based Silica nanoparticles for theranostic applications. Chemistry - A European Journal, 2013, 19 (19), pp.6122-6136. ⟨10.1002/chem.201203003⟩. ⟨hal-00828309⟩
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ref_biblio: Maguy Jaber, François Ribot, Laurent Binet, Valérie Briois, Sophie Cassaignon, et al.. Ex Situ X-ray Diffraction, X-ray Absorption Near Edge Structure, Electron Spin Resonance, and Transmission Electron Microscopy Study of the Hydrothermal Crystallization of Vanadium Oxide Nanotubes: An Insight into the Mechanism of Formation. Journal of Physical Chemistry C, 2012, 117 (10), pp.5446-5452. ⟨10.1021/jp3091039⟩. ⟨hal-00836877⟩
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ref_biblio: Olivia de Los Cobos, B. Fousseret, Martine Lejeune, Fabrice Rossignol, Maggy Colas, et al.. Tunable Multifunctional Mesoporous Silica Microdots Arrays by Combination of Inkjet Printing, EISA, and Click Chemistry. Chemistry of Materials, 2012, 24, pp.4337-4342. ⟨10.1021/cm3022769⟩. ⟨hal-00749574⟩
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ref_biblio: Adam Strachota, François Ribot, Libor Matejka, Paul Whelan, Larisa Starovoytova, et al.. Preparation of Novel, Nanocomposite Stannoxane-Based Organic-Inorganic Epoxy Polymers containing Ionic bonds. Macromolecules, 2012, 45 (1), pp.221-237. ⟨10.1021/ma201178j⟩. ⟨hal-01461433⟩
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ref_biblio: Fabien Périneau, Guangjun Hu, Laurence Rozes, François Ribot, Clément Sanchez, et al.. Synthesis, characterization, and rheological properties of hybrid titanium star‐shaped poly(n‐butyl acrylate). Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49 (12), pp.2636--2644. ⟨10.1002/pola.24695⟩. ⟨hal-01696709⟩
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ref_biblio: David Grosso, François Ribot, Cédric Boissière, Clément Sanchez. Molecular and supramolecular dynamics of hybrid organic–inorganic interfaces for the rational construction of advanced hybrid nanomaterials. Chemical Society Reviews, 2011, 40 (2), pp.829-848. ⟨10.1039/c0cs00039f⟩. ⟨hal-02435807⟩
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ref_biblio: A.A. Letailleur, François Ribot, Cédric Boissière, Jérémie Teisseire, Etienne Barthel, et al.. Sol-Gel Derived Hybrid Thin Films: The Chemistry behind Processing. Chemistry of Materials, 2011, 23 (22), pp.5082-5089. ⟨10.1021/cm202755g⟩. ⟨hal-00647024⟩
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ref_biblio: Fabien Périneau, Sandrine Pensec, Capucine Sassoye, François Ribot, Luk Van Lokeren, et al.. New hybrid core–shell star‐like architectures made of poly(n‐butyl acrylate) grown from well‐defined titanium oxo‐clusters. Journal of Materials Chemistry, 2011, 21 (12), pp.4470. ⟨10.1039/c0jm04047a⟩. ⟨hal-01696708⟩
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ref_biblio: Laetitia Renard, Hicham Elhamzaoui, Bernard Jousseaume, Thierry Toupance, Guillaume Laurent, et al.. Low-temperature H2 sensing in self-assembled organotin thin films. Chemical Communications, 2011, 47 (5), pp.1464-1466. ⟨10.1039/C0CC04188B⟩. ⟨hal-01521053⟩
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ref_biblio: L. van Lokeren, R. Willem, D. van Deer Beek, P. Davidson, G. Morris, et al.. Probing the Anions Mediated Associative Behavior of Tin-12 Oxo-Macrocations by Pulsed Field Gradient NMR Spectroscopy.. Journal of Physical Chemistry C, 2010, 114 (08), pp.16087-16091. ⟨10.1021/jp100709j⟩. ⟨hal-00525267⟩
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ref_biblio: C. Sanchez, L. Rozes, François Ribot, C. Laberty-Robert, D. Grosso, et al.. “Chimie douce”: A land of opportunities for the designed construction of functional inorganic and hybrid organic-inorganic nanomaterials. Comptes Rendus. Chimie, 2010, 13 (1-2), pp.3-39. ⟨10.1016/j.crci.2009.06.001⟩. ⟨hal-02435816⟩
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ref_biblio: B. Fousseret, M. Mougenot, Fabrice Rossignol, Jean-François Baumard, Bernard Soulestin, et al.. Ink-jet printing engineered functional microdot arrays made of mesoporous hybrid organosilicas. Chemistry of Materials, 2010, 22, pp.3875-3883. ⟨10.1021/cm903713q⟩. ⟨hal-00559031⟩
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ref_biblio: F. Mammeri, Christian Bonhomme, F. Ribot, F. Babonneau, S. Dirè. New Monofunctional POSS and Its Utilization as Dewetting Additive in Methacrylate Based Free-Standing Films.. Chemistry of Materials, 2009, 21, pp.4163-4171. ⟨10.1021/cm900339h⟩. ⟨hal-00421891⟩
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ref_biblio: S. de Monredon-Senani, Christian Bonhomme, F. Ribot, F. Babonneau. Covalent grafting of organoalkoxysilanes on silica surfaces in water-rich medium as evidenced by 29 Si NMR. Journal of Sol-Gel Science and Technology, 2009, 50, pp.152-157. ⟨10.1007/S10971-009-1920-7⟩. ⟨hal-00411126⟩
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ref_biblio: M. Blug, M. Doux, X. F Le Goff, P. Maître, F. Ribot, et al.. The Effect of a Fourth Binding Site on the Stabilization of Cationic SPS Pincer Palladium Complexes : Experimental, DFT, and Mass Spectrometric Studies. Organometallics, 2009, 28, pp.2020-2027. ⟨10.1021/om800690t⟩. ⟨hal-00411129⟩
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ref_biblio: Doru Constantin, Brigitte Pansu, Marianne Impéror, Patrick Davidson, François Ribot. Repulsion Between Inorganic Particles Inserted Within Surfactant Bilayers. Physical Review Letters, 2008, 101, pp.098101. ⟨10.1103/PhysRevLett.101.098101⟩. ⟨hal-00315744⟩
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ref_biblio: François Ribot, E. Martinez-Ferrero, K. Boubekeur, P. Hendrickx, J. Martins, et al.. Sn12O8(OH)4(OEt)28(HOEt) 4 : an Additional Member in the Family of Dodecameric Oxo Clusters. Inorganic Chemistry, 2008, 47 (13), pp.5831-5840. ⟨10.1021/ic800123z⟩. ⟨hal-02435820⟩
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ref_biblio: F. Carn, N. Steunou, M. Djabourov, T. Coradin, F. Ribot, et al.. First example of biopolymer-polyoxometalate complex coacervation in gelatin-decavanadate mixtures.. Soft Matter, 2008, 4, pp.735-738. ⟨hal-00347607⟩
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ref_biblio: L. V. Lokeren, G. Maheut, F. Ribot, V. Escax, I. Verbruggen, et al.. Characterization of titanium dioxide nanoparticles dispersed in organic ligand solutions by using a diffusion-ordered spectroscopy-based strategy.. Chemistry - A European Journal, 2007, 13, pp.6957-6966. ⟨hal-00327465⟩
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ref_biblio: M. Nazarely, Corinne Chanéac, F. Ribot, G. Wallez, M. Quarton, et al.. A new history in the structural chemistry of cerium(IV) phosphate. Journal of Physics and Chemistry of Solids, 2007, 68, pp.795-798. ⟨hal-00327480⟩
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ref_biblio: M. Nazarely, M. Quarton, G. Wallez, Corinne Chanéac, F. Ribot, et al.. Ce(H2O)(PO4)3/2(H3O)1/2(H2O)1/2, a second entry in the structural chemistry of cerium(IV) phosphates.. Solid State Sciences, 2007, 9, pp.672-677. ⟨hal-00327475⟩
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ref_biblio: Micaela Nazaraly, Gilles Wallez, Corinne Chanéac, Elisabeth Tronc, François Ribot, et al.. Synthesis and characterization of CeIV(PO4)(HPO4)0.5(H2O)0.5. Journal of Physics and Chemistry of Solids, 2006, 67 (5-6), pp.1075-1078. ⟨10.1016/j.jpcs.2006.01.028⟩. ⟨hal-02435828⟩
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ref_biblio: I. Bardez, D. Caurant, J. L. Dussossoy, P. Loiseau, C. Gervais, et al.. Development and Characterization of Rare Earth-Rich Glassy Matrices Envisaged for the Immobilization of Concentrated Nuclear Waste Solutions. Nuclear Science and Engineering, 2006, 153, pp.272-284. ⟨hal-00114309⟩
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ref_biblio: Eugenia Martinez-Ferrero, Kamal Boubekeur, François Ribot. Carboxylate-containing Tin(IV) isopropoxides : synthesis and characterization of [Sn(OiPr)2(O2CR)2]2 [R=(CH3)CCH2, C6H5, CH3]. European Journal of Inorganic Chemistry, 2006, ?, pp.802-807. ⟨hal-00080363⟩
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ref_biblio: M. Mougenot, Martine Lejeune, Jean-François Baumard, C. Boissiere, F. Ribot, et al.. Ink Jet Printing of Microdot Arrays of Mesostructured Silica. Journal of the American Ceramic Society, 2006, 89, pp.1876-1882. ⟨10.1111/j.1551-2916.2006.01048.x⟩. ⟨hal-00782114⟩
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ref_biblio: Micaela Nazaraly, Gilles Wallez, Corinne Chanéac, Elisabeth Tronc, François Ribot, et al.. The First Structure of a Cerium(IV) Phosphate: Ab Initio Rietveld Analysis of CeIV(PO4)(HPO4)0.5(H2O)0.5. Angewandte Chemie International Edition, 2005, 44 (35), pp.5691-5694. ⟨10.1002/anie.200501871⟩. ⟨hal-02435833⟩
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ref_biblio: I. Bardez, D. Caurant, P. Loiseau, N. Baffier, J. L. Dussossoy, et al.. Structural characterisation of rare earth rich glasses for nuclear waste immobilisation. Physics and Chemistry of Glasses, 2005, 46, pp.320-329. ⟨hal-00023497⟩
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ref_biblio: François Ribot, Delphine Veautier, Steven Guillaudeu, Thierry Lalot. Poly[{(BuSn)12O14(OH)6}(AMPS)2] and poly[methyl acrylate-co-{(BuSn)12O14(OH)6}(AMPS)2]: hybrid polymers cross-linked through electrostatic interactions. Journal of Materials Chemistry, 2005, 15 (35-36), pp.3973-3978. ⟨10.1039/b507214j⟩. ⟨hal-02435836⟩
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ref_biblio: François Ribot, Virginie Escax, Claire Roiland, Clément Sanchez, José C. Martins, et al.. In situ evaluation of interfacial affinity in CeO2 based hybrid nanoparticles by pulsed field gradient NMR. Chemical Communications, 2005, 1, pp.1019-1021. ⟨hal-00077344⟩
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ref_biblio: François Ribot, Delphine Veautier, Steve Guillaudeu, Thierry Lalot. Hybrid Organic-Inorganic Materials Based on Nanobuilding Blocks Assembled through Electrostatic Interactions. Journal of Sol-Gel Science and Technology, 2004, 32 (1-3), pp.37-41. ⟨10.1007/S10971-004-5761-0⟩. ⟨hal-02435841⟩
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ref_biblio: Jens Beckmann, Dainis Dakternieks, Andrew Duthie, Cassandra Mitchell, François Ribot, et al.. Solid-state NMR study of[(Ph3SnF)2(Ph3SnO2PPh2)], a novel coordination polymer prepared from Bu4N[Ph3SnF2] and[Ph3SnOPPh2OSnPh3](O3SCF3). Applied Organometallic Chemistry, 2004, 18 (7), pp.353-358. ⟨10.1002/aoc.653⟩. ⟨hal-02435842⟩
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ref_biblio: François Ribot, Virginie Escax, José Martins, Monique Biesemans, Laurent Ghys, et al.. Probing Ionic Association on Metal Oxide Clusters by Pulsed Field Gradient NMR Spectroscopy: The Example of Sn12–Oxo Clusters. Chemistry - A European Journal, 2004, 10 (7), pp.1747-1751. ⟨10.1002/chem.200305604⟩. ⟨hal-02435844⟩
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ref_biblio: Jens Beckmann, Dainis Dakternieks, Andrew Duthie, François Ribot, Markus Schürmann, et al.. New Insights into the Structures of Diorganotellurium Oxides. The First Polymeric Diorganotelluroxane [(p-MeOC6H4)2TeO]n. Organometallics, 2003, 22 (16), pp.3257-3261. ⟨10.1021/om021024c⟩. ⟨hal-02435847⟩
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ref_biblio: Eduardo Crepaldi, Galo Soler-Illia, David Grosso, Florence Cagnol, François Ribot, et al.. Controlled Formation of Highly Organized Mesoporous Titania Thin Films: From Mesostructured Hybrids to Mesoporous Nanoanatase TiO 2. Journal of the American Chemical Society, 2003, 125 (32), pp.9770-9786. ⟨10.1021/ja030070g⟩. ⟨hal-02435846⟩
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ref_biblio: Clément Sanchez, Galo J.de A.A Soler-Illia, François Ribot, David Grosso. Design of functional nano-structured materials through the use of controlled hybrid organic–inorganic interfaces. Comptes Rendus. Chimie, 2003, 6 (8-10), pp.1131-1151. ⟨10.1016/j.crci.2003.06.001⟩. ⟨hal-02435845⟩
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ref_biblio: Sophie de Monredon, Antoine Cellot, François Ribot, Clément Sanchez, Lidia Armelao, et al.. Synthesis and characterization of crystalline tin oxide nanoparticles. Journal of Materials Chemistry, 2003, 12 (8), pp.2396-2400. ⟨10.1039/b203049g⟩. ⟨hal-02435858⟩
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ref_biblio: C. Jousseaume, D. Vivien, A. Kahn-Harari, J. Derouet, François Ribot, et al.. Spectroscopic characterization of chromium (IV, V, VI) in Cr:Li2MSiO4 (M=Mg,Zn). Journal of Applied Physics, 2003, 93 (10), pp.6006-6015. ⟨10.1063/1.1568152⟩. ⟨hal-02435848⟩
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ref_biblio: C. Jousseaume, François Ribot, A. Kahn-Harari, D. Vivien, F. Villain. XAS study of chromium in Li2MSiO4 (M=Mg, Zn). Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2003, 200, pp.425-431. ⟨10.1016/S0168-583X(02)01734-2⟩. ⟨hal-02435852⟩
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ref_biblio: François Ribot, A. Lafuma, C. Eychenne-Baron, C. Sanchez. New Photochromic Hybrid Organic–Inorganic Materials Built from Well-Defined Nano-Building Blocks. Advanced Materials, 2002, 14 (20), pp.1496-1499. ⟨10.1002/1521-4095(20021016)14:20<1496::AID-ADMA1496>3.0.CO;2-N⟩. ⟨hal-02435856⟩
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ref_biblio: Ricardo Vivas-Reyes, Frank de Proft, Paul Geerlings, Monique Biesemans, Rudolph Willem, et al.. A DFT and HF quantum chemical study of the tin nanocluster [(RSn)12O14(OH)6]2+ and its interactions with anions and neutral nucleophiles: confrontation with experimental data. New Journal of Chemistry, 2002, 26 (9), pp.1108-1117. ⟨10.1039/b201328b⟩. ⟨hal-02435861⟩
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ref_biblio: Cecile Jousseaume, Andrée Kahn-Harari, Daniel Vivien, Jacqueline Derouet, François Ribot, et al.. Structural and spectroscopic characterisation of Cr:Li2MgSiO4 (γ0). Journal of Materials Chemistry, 2002, 12 (5), pp.1525-1529. ⟨10.1039/b106707a⟩. ⟨hal-02435864⟩
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ref_biblio: François Ribot, Christophe Eychenne-Baron, Franck Fayon, Dominique Massiot, Bruno Bresson. 119Sn Solid state NMR characterization of BuSnO(OH). Main Group Metal Chemistry, 2002, 25 (1), pp.115-119. ⟨hal-02435871⟩
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ref_biblio: C. Sanchez, G. Soler-Illia, François Ribot, T. Lalot, C. Mayer, et al.. Designed Hybrid Organic−Inorganic Nanocomposites from Functional Nanobuilding Blocks. Chemistry of Materials, 2001, 13 (10), pp.3061-3083. ⟨10.1021/CM011061E⟩. ⟨hal-02435873⟩
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ref_biblio: François Ribot, Clément Sanchez, Monique Biesemans, Frédéric A.G. Mercier, José C. Martins, et al.. Di-n-butyltin Methyl- and Phenylphosphonates. Organometallics, 2001, 20 (12), pp.2593-2603. ⟨10.1021/OM010140X⟩. ⟨hal-02435874⟩
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ref_biblio: Christophe Eychenne-Baron, François Ribot, Nathalie Steunou, Clément Sanchez, Franck Fayon, et al.. Reaction of Butyltin Hydroxide Oxide with p -Toluenesulfonic Acid: Synthesis, X-ray Crystal Analysis, and Multinuclear NMR Characterization of {(BuSn)12O14(OH)6}(4-CH3C6H4SO3)2. Organometallics, 2000, 19 (10), pp.1940-1949. ⟨10.1021/om990877a⟩. ⟨hal-02435882⟩
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ref_biblio: Juliette Blanchard, François Ribot, Clément Sanchez, Pierre-Vincent Bellot, Arlette Trokiner. Structural characterization of titanium-oxo-polymers synthesized in the presence of protons or complexing ligands as inhibitors. Journal of Non-Crystalline Solids, 2000, 265 (1-2), pp.83-97. ⟨10.1016/S0022-3093(99)00885-6⟩. ⟨hal-02435887⟩
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ref_biblio: C. Sanchez, F. Ribot, L. Rozes, B. Alonso. Design of Hybrid Organic-Inorganic Nanocomposites Synthesized Via Sol-Gel Chemistry. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 2000, 354 (1), pp.143-158. ⟨10.1080/10587250008023609⟩. ⟨hal-02049332⟩
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ref_biblio: C. Sanchez, B. Lebeau, François Ribot, Martin In. Molecular design of sol-gel derived hybrid organic-inorganic nanocomposites. Journal of Sol-Gel Science and Technology, 2000, 19 (1/3), pp.31-38. ⟨10.1023/A:1008753919925⟩. ⟨hal-02435879⟩
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ref_biblio: François Ribot, Christophe Eychenne-Baron, Clément Sanchez. Monoorganotin Oxo-Clusters : Versatile Nanobuilding Blocks for Hybrid Organic-Inorganic Materials. Phosphorus, Sulfur, and Silicon and the Related Elements, 1999, 150 (1), pp.41-58. ⟨10.1080/10426509908037039⟩. ⟨hal-02437415⟩
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ref_biblio: François Ribot, C. Sanchez. Organically Functionalized Metallic Oxo-Clusters: Structurally Well-Defined Nanobuilding Blocks for the Design of Hybrid Organic-Inorganic Materials. Comments on Inorganic Chemistry, 1999, 20 (4-6), pp.327-371. ⟨10.1080/02603599908021449⟩. ⟨hal-02436403⟩
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ref_biblio: C. Sanchez, François Ribot, B. Lebeau. Molecular design of hybrid organic-inorganic nanocomposites synthesized via sol-gel chemistry. Journal of Materials Chemistry, 1999, 9 (1), pp.35-44. ⟨10.1039/A805538F⟩. ⟨hal-02436400⟩
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ref_biblio: Nathalie Steunou, François Ribot, Kamal Boubekeur, Jocelyne Maquet, Clément Sanchez. Ketones as an oxolation source for the synthesis of titanium-oxo-organoclusters. New Journal of Chemistry, 1999, 23 (11), pp.1079-1086. ⟨10.1039/A904760C⟩. ⟨hal-02436394⟩
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ref_biblio: Nathalie Steunou, Francis Robert, Kamal Boubekeur, François Ribot, Clément Sanchez. Synthesis through an in situ esterification process and characterization of oxo isopropoxo titanium clusters. Inorganica Chimica Acta Reviews, 1998, 279 (2), pp.144-151. ⟨10.1016/S0020-1693(98)00109-1⟩. ⟨hal-02437428⟩
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ref_biblio: C. Eychenne-Baron, François Ribot, C. Sanchez. New synthesis of the nanobuilding block {(BuSn)12O14(OH)6}2+and exchange properties of {(BuSn)12O14(OH)6}(O3SC6H4CH3)2. Journal of Organometallic Chemistry, 1998, 567 (1-2), pp.137-142. ⟨10.1016/S0022-328X(98)00676-7⟩. ⟨hal-02437360⟩
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ref_biblio: K. Dardenne, D. Vivien, François Ribot, G. Chottard, D. Huguenin. Mn(V) polyhedron size in Ba10((P,Mn)O4)6F2: vibrational spectroscopy and EXAFS study. European Journal of Solid State and Inorganic Chemistry, 1998, 35 (6-7), pp.419-431. ⟨10.1016/S0992-4361(98)80020-9⟩. ⟨hal-02437355⟩
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ref_biblio: François Ribot, Clément Sanchez, Rudolph Willem, José C Martins, Monique Biesemans. Solution and Solid State Multinuclear NMR Investigation of the Structure of {(BuSn)12O14(OH)6}(O2PPh2)2. Inorganic Chemistry, 1998, 37 (5), pp.911-917. ⟨10.1021/IC971189R⟩. ⟨hal-02437438⟩
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ref_biblio: François Ribot, Clément Sanchez, Abdelkrim Meddour, Marcel Gielen, Edward R.T Tiekink, et al.. On the assignment of 119Sn resonances of bis[dicarboxylatotetraorganodistannoxanes] in solution and solid state 119Sn NMR spectra. Journal of Organometallic Chemistry, 1998, 552 (1-2), pp.177-186. ⟨10.1016/S0022-328X(97)00569-X⟩. ⟨hal-02437433⟩
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ref_biblio: Pascale Jaumier, Bernard Jousseaume, Mohammed Lahcini, François Ribot, Clément Sanchez. New route to monoorganotin oxides and alkoxides from trialkynylorganotins. Chemical Communications, 1998, 3, pp.369-370. ⟨10.1039/A707298H⟩. ⟨hal-02437448⟩
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ref_biblio: Rudolph Willem, Abdeslam Bouhdid, Abdelkrim Meddour, Carlos Camacho-Camacho, Frédéric Mercier, et al.. X-ray Diffraction and 2D Gradient-Assisted 1H−119 Sn HMQC NMR Studies of Structures Obtained from Nucleophilic Substitutions on Dimethyltin(IV) Salicylaldoximates. Organometallics, 1997, 16 (20), pp.4377-4385. ⟨10.1021/OM970378E⟩. ⟨hal-02438046⟩
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ref_biblio: François Ribot, F. Banse, C. Sanchez, M. Lahcini, B. Jousseaume. Hybrid organic-inorganic copolymers based on oxo-hydroxo organotin nanobuilding blocks. Journal of Sol-Gel Science and Technology, 1997, 8 (1-3), pp.529-533. ⟨10.1007/BF02436894⟩. ⟨hal-02438056⟩
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ref_biblio: Rudolph Willem, Hassan Dalil, Paul Broekaert, Monique Biesemans, Laurent Ghys, et al.. Di-n-Butyl-, tri-n-Butyl- and triphenyltin steroidcarboxylates : Synthesis, NMR characterization and in vitro antitumour actibvity. Main Group Metal Chemistry, 1997, 20 (8), pp.535-542. ⟨10.1515/MGMC.1997.20.8.535⟩. ⟨hal-02438118⟩
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ref_biblio: L. Angiolini, D. Caretti, R. de Vito, F. Niesel, E. Salatelli, et al.. Hybrid organic-inorganic copolymers from oxo-hydroxo organotin dimethacrylate and methylmethacrylate. Journal of Inorganic and Organometallic Polymers, 1997, 7 (3), pp.151-162. ⟨10.1023/A:1021634305797⟩. ⟨hal-02437468⟩
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ref_biblio: Fréderic Banse, François Ribot, P. Toledano, J. Maquet, C. Sanchez. Hydrolysis of Monobutyltin Trialkoxides: Synthesis and Characterizations of {(BuSn)12O14(OH)6}(OH)2. Inorganic Chemistry, 1995, 34 (25), pp.6371-6379. ⟨10.1021/IC00129A023⟩. ⟨hal-02438127⟩
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ref_biblio: B Garcia, Philippe Barboux, François Ribot, Andrée Kahn-Harari, Leo Mazerolles, et al.. The structure of low temperature crystallized LiCoO2. Solid State Ionics, 1995, 80 (1-2), pp.111-118. ⟨10.1016/0167-2738(95)00117-O⟩. ⟨hal-02438153⟩
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ref_biblio: P. Barboux, P. Griesmar, François Ribot, L. Mazerolles. Homogeneity-Related Problems in Solution Derived Powders. Journal of Solid State Chemistry, 1995, 117 (2), pp.343-350. ⟨10.1006/JSSC.1995.1283⟩. ⟨hal-02438177⟩
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ref_biblio: Bernard Jousseaume, Mohammed Lahcini, Marie-Claude Rascle, François Ribot, Clément Sanchez. General Routes to Functional Organotin Trichlorides and Trialkoxides Involving the Tricyclohexylstannyl Group. Organometallics, 1995, 14 (2), pp.685-689. ⟨10.1021/OM00002A016⟩. ⟨hal-02438190⟩
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ref_biblio: François Ribot, Fréderic Banse, Fleur Diter, Clément Sanchez. Hybrid organic-inorganic supramolecular assemblies made of butyl tin oxo-hydroxo nano building blocks and dicarboxylates. New Journal of Chemistry, 1995, 19 (11), pp.1145-1153. ⟨hal-02438229⟩
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ref_biblio: C. Schmutz, P. Barboux, François Ribot, F. Taulelle, M. Verdaguer, et al.. EXAFS, Raman and 31P NMR study of amorphous titanium phosphates. Journal of Non-Crystalline Solids, 1994, 170 (3), pp.250-262. ⟨10.1016/0022-3093(94)90054-X⟩. ⟨hal-02438289⟩
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ref_biblio: C. Sanchez, B. Alonso, F. Chapusot, F. Ribot, P. Audebert. Molecular design of hybrid organic-inorganic materials with electronic properties. Journal of Sol-Gel Science and Technology, 1994, 2 (1-3), pp.161-166. ⟨10.1007/BF00486233⟩. ⟨hal-02049341⟩
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ref_biblio: Clément Sanchez, François Ribot. Design of hybrid organic-inorganic materials synthesized via sol-gel chemistry. New Journal of Chemistry, 1994, 18 (10), pp.1007-1047. ⟨hal-02438304⟩
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ref_biblio: G Monros, J Carda, M. Tena, P. Escribano, François Ribot, et al.. Vanadium clusters in doped ZrO2-SiO2 toughened ceramic composites obtained from alkoxides. Solid State Ionics, 1993, 63-65, pp.218-225. ⟨10.1016/0167-2738(93)90110-O⟩. ⟨hal-02438411⟩
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ref_biblio: Clément Sanchez, F. Ribot. Molecular design of hybrid organic-inorganic materials. Journal de Physique IV Proceedings, 1993, 03 (C7), pp.C7-1349-C7-1355. ⟨10.1051/jp4:19937207⟩. ⟨jpa-00251841⟩
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ref_biblio: François Ribot, P. Toledano, C. Sanchez. X-ray and spectroscopic investigations of the structure of yttrium acetate tetrahydrate. Inorganica Chimica Acta Reviews, 1991, 185 (2), pp.239-245. ⟨10.1016/S0020-1693(00)85449-3⟩. ⟨hal-02438420⟩
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ref_biblio: François Ribot, Paul Toledano, Clément Sanchez. Hydrolysis-condensation process of beta-diketonates-modified cerium(IV) isopropoxide. Chemistry of Materials, 1991, 3 (4), pp.759-764. ⟨10.1021/CM00016A035⟩. ⟨hal-02438504⟩
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ref_biblio: P. Toledano, François Ribot, C. Sanchez. Structure of bis(2-propanol)-bis-μ-(2-propanolato)-hexakis(2-propanolato)dicerium(IV). Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], 1990, 46 (8), pp.1419-1422. ⟨10.1107/S0108270189012564⟩. ⟨hal-02438568⟩
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ref_biblio: Paul Toledano, François Ribot, Clément Sanchez. Synthèse et structure de composé [Ce6(µ3-O)4(µ3-OH)4(acac)12]. Comptes Rendus de l'Académie des Sciences de Paris.Série 2 : Sciences de la Terre et des Planètes, 1990, 311, pp.1315-1320. ⟨hal-02438537⟩
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ref_biblio: François Ribot, Stanka Kratohvil, Egon Matijevic. Preparation and properties of uniform mixed colloidal particles: IV, Copper(II)-Yttrium(III) and Copper(II)-Lanthanum(III) compounds. Journal of Materials Research, 1989, 4 (5), pp.1123-1131. ⟨hal-02438610⟩
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Book sections

ref_biblio: Bruno Alonso, Christian Bonhomme, Christel Gervais, Flavien Guenneau, Danielle Laurencin, et al.. Nuclear Magnetic Resonance as a Tool for the Investigation of Interfaces and Textures in Nanostructured Hybrid Materials. Hybrid Organic-Inorganic Interfaces: Towards Advanced Functional Materials, 2017, ⟨10.1002/9783527807130.ch20⟩. ⟨hal-01936830⟩
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ref_biblio: Sandra Diré, Evgeny Borovin, François Ribot. Architecture of Silsesquioxanes. Handbook of Sol-Gel Science and Technology, Springer International Publishing, pp.1-34, 2016, ⟨10.1007/978-3-319-19454-7_119-1⟩. ⟨hal-02435889⟩
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ref_biblio: François Ribot. Mono-organotin oxo-clusters. A.G. Davies; M. Gielen; K.H. Pannell; E.R.T. Tiekink. Tin Chemistry: Fundamentals, Frontiers, and Applications, Wiley, pp.69-92, 2008, 978-0-470-51771-0. ⟨hal-02435891⟩
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ref_biblio: François Ribot, Clément Sanchez, Jacques Livage. Tailoring of cerium(IV) oxide precursors through modification of cerium(IV) isopropoxide with ß diketones. L.L Hench; J.K. West. Chemical Processing of Advanced Materials, John Wiley & Sons, pp.267-275, 1992, 978-0471542018. ⟨hal-02435930⟩
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ref_biblio: Clément Sanchez, François Ribot, Sylvie Doeuff. Transition metal oxo-polymers synthesised via sol-gel chemistry. R.M. Laine. Inorganic and Organometallic Polymers with Special Properties, Kluwer Academic, pp.267-295, 1992, 978-94-011-2612-0. ⟨hal-02435900⟩
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Patents

ref_biblio: Loïc Marchin, Marie-Laure Desse, Alexandre Perrot, François Ribot, Sophie Senani, et al.. Particules mésostructurées chargées en agents anticorrosion obtenues par aerosol. France, N° de brevet: WO2016097558. 2016. ⟨hal-02435922⟩
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ref_biblio: Sophie Senani, Loïc Marchin, Marie-Laure Desse, Lionel Nicole, François Ribot, et al.. Revêtements anticorrosion chargés en particules mésostructurées. France, N° de brevet: WO2016097570. 2016. ⟨hal-02435924⟩
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ref_biblio: Sophie de Monredon - Senani, Elisa Campazzi, Clément Sanchez, Lionel Nicole, François Ribot. Revêtements mésostructurés comprenant un agent texturant particulier, pour application en aéronautique et aérospatiale. France, N° de brevet: WO2009136044. 2009. ⟨hal-02435919⟩
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None for the moment

Last update 2020/08/03

Last update on 2020/08/03